Product Name: Refining Additive-A100
Chemical Family: Hydrocarbon Derivatives
Recommended Use: Catalysis in Petrochemical Processing
Supplier: Global Refining Chemicals Ltd., 25 Industrial Drive, Houston, TX, USA
Emergency Telephone: 1-800-555-1133
Synonyms: Hydrocracking Agent, HD Catalyst Booster
Product Code: A100-CAT-005
Date Prepared: 2024-04-12
Revised Date: 2024-06-10
Contact Email: msds@globalrefining.com
Hazard Classification: Flammable Liquid - Category 3; Acute Toxicity (Oral) - Category 4; Skin Irritant - Category 2; Eye Irritant - Category 2A
Label Elements: Signal Word: Warning, Hazard Pictograms: Flame, Exclamation Mark
Hazard Statements: Causes skin and eye irritation; Harmful if swallowed; Flammable liquid and vapor
Precautionary Statements: Keep away from heat/sparks/open flames/hot surfaces; Avoid breathing vapors; Wear protective gloves; Wash hands thoroughly after handling
NFPA Ratings: Health: 2, Flammability: 3, Reactivity: 1
Routes of Entry: Inhalation, Skin, Eye Contact, Ingestion
Main Ingredients: Alkylated Aromatic Hydrocarbons (CAS # 68608-96-0): 45-55%; Proprietary Zeolite Complex (CAS # 1332-09-4): 40-50%; Silica Additive (CAS # 7631-86-9): 1-5%
Impurities: Trace Benzene < 0.1% (CAS # 71-43-2); Sulfur Compounds < 0.5%
Stabilizers/Additives: None present in reportable concentrations
Exposure Limits: OSHA PEL for total hydrocarbons: 300 ppm; Zeolite: 10 mg/m³ (respirable)
Inhalation: Move person to fresh air immediately; supply oxygen if breathing is difficult; seek medical attention if symptoms persist
Skin Contact: Wash affected skin thoroughly with soap and water for at least 15 minutes; remove contaminated clothing and wash before reuse
Eye Contact: Flush eyes with lukewarm water for at least 15-20 minutes while holding eyelids open; remove contact lenses if present and easy to do
Ingestion: Rinse mouth with water; Do not induce vomiting; Get medical attention promptly
Key Symptoms/Effects: Irritation, headache, nausea, dizziness, redness, burning sensation
Suitable Extinguishing Media: Foam, dry chemical, carbon dioxide, water spray
Unsuitable Media: Do not use water jet
Specific Hazards: Vapors may form explosive mixtures with air; containers may rupture in fire
Protective Equipment: Self-contained breathing apparatus and full turnout gear
Firefighting Instructions: Cool fire-exposed containers with water spray; avoid breathing vapors; evacuate area if necessary
Personal Precautions: Ventilate area; avoid contact with skin and eyes; evacuate non-essential personnel
Protective Gear: Chemical-resistant gloves, goggles, protective clothing, respirator if required
Spill Containment: Dike and contain spill with inert materials (sand, earth)
Cleanup Procedures: Absorb with non-combustible material; collect in sealed containers for disposal; clean surface with detergent and water
Environmental Precautions: Prevent entry into waterways, drains, or soil
Handling: Avoid inhalation and personal contact with liquid; operate with proper ventilation; ground and bond containers when transferring product
Storage Conditions: Store in tightly closed containers away from heat, sparks, or open flame in a cool, dry, well-ventilated location
Incompatible Materials: Strong oxidizers, acids, alkalis; avoid mixing with reactive metals
Bulk Storage Requirements: Use approved containers, keep away from ignition sources; inspect storage area for leaks and damage regularly
Hygiene Practices: Wash hands after use; do not eat, drink, or smoke while handling this material
Engineering Controls: Local exhaust ventilation and general ventilation in the work area; use explosion-proof electrical equipment
Hand Protection: Nitrile or neoprene gloves recommended
Eye Protection: Safety goggles or full face shield
Respiratory Protection: Use an approved organic vapor respirator if airborne concentrations exceed limits
Skin and Body Protection: Long-sleeve chemical-resistant clothing and safety boots
Occupational Exposure Limits: OSHA PELs and ACGIH TLVs for specific hydrocarbon and zeolite components apply
Appearance: Slightly viscous amber to light brown liquid
Odor: Petroleum-like, mild hydrocarbon smell
Odor Threshold: 0.1-0.5 ppm (hydrocarbons)
pH: Not applicable
Melting/Freezing Point: -25°C
Boiling Point/Ranges: 165°C – 235°C
Flash Point: 42°C (closed cup)
Evaporation Rate: 0.8 (butyl acetate = 1)
Flammability: Flammable
Vapor Pressure: 1.7 mmHg @ 25°C
Vapor Density: >1 (air = 1)
Relative Density: 0.88 g/cm³ @ 20°C
Solubility in Water: Insoluble
Partition Coefficient (n-octanol/water): >3.5
Auto-ignition Temperature: 310°C
Decomposition Temperature: Not determined
Viscosity: 12 mPa·s @ 25°C
Chemical Stability: Stable at normal temperature and under recommended storage conditions
Reactive Hazards: Reacts with strong oxidizers, acids, and alkalis; avoid contact with reactive metals like sodium
Conditions to Avoid: Heat, sparks, open flames, static discharge
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, low levels of sulfur oxides during combustion
Polymerization: Not likely under normal conditions but avoid mixing with incompatible materials
Acute Toxicity: Oral LD50 (rat): 1700 mg/kg; Dermal LD50 (rabbit): >2000 mg/kg
Skin Corrosion/Irritation: Moderately irritating based on animal studies
Serious Eye Damage/Irritation: Causes eye irritation
Respiratory or Skin Sensitization: Not expected to cause sensitization
Chronic Effects: Prolonged contact may cause dermatitis; long-term inhalation linked to mild respiratory irritation
Carcinogenicity: Not classified as carcinogenic (IARC, NTP, OSHA); contains trace benzene, a known carcinogen, below reportable thresholds
Mutagenicity: Not mutagenic in standard tests
Reproductive Toxicity: No information indicating reproductive hazard at expected exposures
Ecotoxicity: Harmful to aquatic life with long lasting effects; LC50 (Fish, 96 h): 8.4 mg/L; EC50 (Daphnia, 48 h): 11 mg/L
Persistence and Degradability: Not rapidly biodegradable; hydrocarbon component may persist in environment
Bioaccumulative Potential: High, due to log Kow > 3.5 in main hydrocarbon fraction
Soil Mobility: Low mobility; potential to adsorb onto soil particles
Other Harmful Effects: Contaminates ground and surface waters in large spills; avoid unintentional release to the environment
Waste Treatment Methods: Incinerate in a facility equipped for chemical waste; do not dispose to landfill without treatment
Contaminated Packaging: Triple rinse containers before disposal or recycling; follow local regulations
Special Precautions: Prevent residue runoff into sewer or water systems
Regulatory Status: Dispose as hazardous waste according to local, state, and federal regulations
Recommended Disposal Agencies: Licensed hazardous waste recycler or incinerator contractor
UN Number: UN 1993
Proper Shipping Name: Flammable Liquid, N.O.S. (Alkylated Aromatic Hydrocarbons, Zeolite Complex)
Transport Hazard Class: 3 (Flammable Liquid)
Packing Group: III
Label Requirements: Class 3 Flammable Liquid; Marine Pollutant
Special Precautions: Avoid release into environment; keep containers upright and protected from physical damage
ADR/RID, IMDG, IATA Compliance: Regulated as flammable liquid for road, sea, and air transit
OSHA Hazard Communication Standard: Meets requirements for hazardous chemical
TSCA Inventory: All ingredients listed or exempt
SARA Title III (EPCRA): Section 311/312: Fire, Acute Health Hazard; Section 313: Contains Benzene (<0.1%) - reportable
California Proposition 65: Contains a chemical known to the State of California to cause cancer (benzene)
REACH Compliance: Registered under EU REACH regulation
WHMIS Classification (Canada): Class B2 (Flammable Liquid), D2B (Toxic Material with Other Toxic Effects)
Other Regulations: Not listed as PBT or vPvB; complies with applicable local chemical safety statutes
